IRON Laboratories     PJLA

ISO/IEC 17025:2017 Accredited

Pesticide Analysis by
Mass Spectrometer
Testing Accreditation #: 77802 Test Certificate #: 133976-001
Client Name, Sample Details

George Investments
Westland, MI 48186
Sample: 47
Type: Concentrate
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS211116A
Scale: XS205-MI1
Temp: 20.3 °C
Baro PE: 984.7 hPa
Analyst: MEH
Technician: ACT
Sample ID#: 133976

Harvest/Process Date: 11/10/2021
Date Received: 11/10/2021
Test Date: 11/16/2021
Valid Through: 11/16/2022
Report Issued: 11/17/2021
Sample #133976
Compound MRL (µg/g) LOD (µg/g) Status (µg/g)   Compound MRL (µg/g) LOD (µg/g) Status (µg/g)
Aldicarb 0.400 0.125 Pass/<LOD Abamectin**** 0.500 0.125 Pass/<LOD
Acephate 0.400 0.125 Pass/<LOD Acequinocyl 2.000 0.250 Pass/<LOD
Acetamiprid 0.200 0.125 Pass/<LOD Azoxystrobin 0.200 0.125 Pass/<LOD
Bifenazate 0.200 0.125 Pass/<LOD Bifenthrin 0.200 0.125 Pass/<LOD
Boscalid 0.400 0.125 Pass/<LOD Carbaryl 0.200 0.125 Pass/<LOD
Carbofuran 0.200 0.125 Pass/<LOD Chlorantraniliprole 0.200 0.125 Pass/<LOD
Chlorfenapyr 1.000 0.500 Pass/<LOD Chlorpyrifos 0.200 0.125 Pass/<LOD
Clofentezine 0.200 0.125 Pass/<LOD Cyfluthrin** 1.000 0.500 Pass/<LOD
Cypermethrin*** 1.000 0.500 Pass/<LOD Daminozide 1.000 0.500 Pass/<LOD
DDVP (Dichlorvos) 1.000 0.250 Pass/<LOD Diazinon 0.200 0.125 Pass/<LOD
Dimethoate 0.200 0.125 Pass/<LOD Ethoprophos 0.200 0.125 Pass/<LOD
Etofenprox 0.400 0.125 Pass/<LOD Etoxazole 0.200 0.125 Pass/<LOD
Fenoxycarb 0.200 0.125 Pass/<LOD Fenpyroximate 0.400 0.125 Pass/<LOD
Fipronil 0.400 0.125 Pass/<LOD Flonicamid 1.000 0.125 Pass/<LOD
Fludioxonil 0.400 0.125 Pass/<LOD Hexythiazox 1.000 0.125 Pass/<LOD
Imazalil 0.200 0.125 Pass/<LOD Imidacloprid 0.400 0.125 Pass/<LOD
Kresoxim Methyl 0.400 0.125 Pass/<LOD Malathion 0.200 0.125 Pass/<LOD
Metalaxyl 0.200 0.125 Pass/<LOD Methiocarb 0.200 0.125 Pass/<LOD
Methomyl 0.400 0.125 Pass/<LOD Methyl Parathion 0.200 0.125 Pass/<LOD
MGK-264‡ 0.200 0.125 Pass/<LOD Myclobutanil 0.200 0.125 Pass/<LOD
Naled 0.500 0.125 Pass/<LOD Oxamyl 1.000 0.125 Pass/<LOD
Paclobutrazol 0.400 0.125 Pass/<LOD Permethrins† 0.200 0.125 Pass/<LOD
Phosmet 0.200 0.125 Pass/<LOD Piperonyl Butoxide 100.000 1.900 Not Tested
Prallethrin 0.200 0.125 Pass/<LOD Propiconazole 0.400 0.125 Pass/<LOD
Propoxur 0.200 0.125 Pass/<LOD Pyrethrins* 1.000 0.125 Pass/<LOD
Pyridaben 0.200 0.125 Pass/<LOD Spinosad***** 0.200 0.125 Pass/<LOD
Spiromesifen 0.200 0.125 Pass/<LOD Spirotetramat 0.200 0.125 Pass/<LOD
Spiroxamine‡ 0.400 0.125 Pass/<LOD Tebuconazole 0.400 0.125 Pass/<LOD
Thiacloprid 0.200 0.125 Pass/<LOD Thiamethoxam 0.200 0.125 Pass/<LOD
Trifloxystrobin 0.200 0.125 Pass/<LOD

* Pyrethrins are reported as the sum of Jasmolin I, Cinerin I, and Pyrethrin I
** Cyfluthrins are reported as the sum of isomers Cyfluthrin I, II, III, and IV
*** Cypermethrins are reported as the sum of isomers Cypermethrin I, II, III, and IV
**** Abamectin is reported as the sum of Avermectin B1a and Avermectin B1b
***** Spinosad is reported as the sum of Spinosyn A and Spinosyn D
† Permethrin and Prallethrin are reported as the sum of cis and trans isomers
‡ MGK-264 and Spiroximine are reported as the sum of isomers I and II
MRL - Maximum Residue Limit; LOD - Limit of Detection

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
KEB - LM Iron laboratories KEB - LM

Iron Laboratories, LLC is an ISO/IEC 17025:2017 Testing Laboratory laboratory accredited by (PJLA) Perry Johnson Laboratory Accreditation, Certificate No. 77802

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

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IRON Laboratories     PJLA

ISO/IEC 17025:2017 Accredited

Pesticide QC Report
Testing Accreditation #: 77802 Test Certificate #: 133976-001
Client Name, Sample Details

George Investments
Westland, MI 48186
Sample: 47
Type: Concentrate
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS211116A
Scale: XS205-MI1
Temp: 20.3 °C
Baro PE: 984.7 hPa
Analyst: MEH
Technician: ACT
Sample ID#: 133976

Harvest/Process Date: 11/10/2021
Date Received: 11/10/2021
Test Date: 11/16/2021
Valid Through: 11/16/2022
Report Issued: 11/17/2021
Sample #133976
Target Compound Name Method Blank (μg/g) QC Spike (μg/g) Matrix Spike (μg/g) Matrix Spike Duplicate (μg/g) MS recovery% MSD recovery% Relative Percent Difference (%) QC Flag
Acephate N.D. 1 1.17 1.41 117.00 141.00 18.60 HR
Acequinocyl N.D. 1 0.607 0.673 60.70 67.30 10.31
Acetamiprid N.D. 1 1.37 1.43 137.00 143.00 4.29 HR
Aldicarb N.D. 1 0.818 1.07 81.80 107.00 26.69
Avermectin B1a N.D. 0.99 1.21 1.41 122.22 142.42 15.27 HR
Azoxystrobin N.D. 1 1.32 1.52 132.00 152.00 14.08 HR
Bifenazate N.D. 1 0.839 1.02 83.90 102.00 19.47
Bifenthrin N.D. 1 1.04 1.26 104.00 126.00 19.13 HR
Boscalid N.D. 1 1.3 1.49 130.00 149.00 13.62 HR
Carbaryl N.D. 1 1.36 1.58 136.00 158.00 14.97 HR
Carbofuran N.D. 1 1.2 1.51 120.00 151.00 22.88 HR
Chlorantraniliprole N.D. 1 1.34 1.66 134.00 166.00 21.33 HR
Chlorfenapyr N.D. 1 0.849 0.785 84.90 78.50 7.83
Chlorpyriphos N.D. 1 1.02 1.19 102.00 119.00 15.38
Clofentezine N.D. 1 1.03 1.27 103.00 127.00 20.87 HR
Cyfluthrin N.D. 1 1.18 1.09 118.00 109.00 7.93
Cypermethrin N.D. 1 1.09 1.15 109.00 115.00 5.36
Daminoside N.D. 1 0.314 0.435 31.40 43.50 32.31 LRQ
Diazanon N.D. 1 1.06 1.28 106.00 128.00 18.80 HR
Dichlorvos N.D. 1 0.977 1.33 97.70 133.00 30.60 HRQ
Dimethoate N.D. 1 1.17 1.27 117.00 127.00 8.20 HR
Ethoprophos N.D. 1 0.841 1 84.10 100.00 17.27
Etofenprox N.D. 1 0.895 1.02 89.50 102.00 13.05
Etoxazole N.D. 1 1.26 1.54 126.00 154.00 20.00 HR
Fenoxycarb N.D. 1 1.33 1.51 133.00 151.00 12.68 HR
Fenpyroximate N.D. 1 1.1 1.32 110.00 132.00 18.18 HR
Fipronil N.D. 1 1.08 1.07 108.00 107.00 0.93
Flonicamid N.D. 1 1.28 1.45 128.00 145.00 12.45 HR
Fludioxonil N.D. 1 1.06 1.08 106.00 108.00 1.87
Hexythiazox N.D. 1 0.893 1.03 89.30 103.00 14.25
Imazalil N.D. 1 1.24 1.54 124.00 154.00 21.58 HR
Imidacloprid N.D. 1 1.44 1.54 144.00 154.00 6.71 HR
Kresoxim-methyl N.D. 1 1.16 1.08 116.00 108.00 7.14
Malathion N.D. 1 1.19 1.37 119.00 137.00 14.06 HR
Metalaxyl N.D. 1 1.29 1.54 129.00 154.00 17.67 HR
Methiocarb N.D. 1 1.04 1.31 104.00 131.00 22.98 HR
Methomyl N.D. 1 1.17 1.56 117.00 156.00 28.57 HR
MGK-264 N.D. 1 0.97 1.15 97.00 115.00 16.98
Myclobutanil N.D. 1 1.54 1.9 154.00 190.00 20.93 HR
Naled (dibrom) N.D. 1 0.849 1.17 84.90 117.00 31.80 Q
Oxamyl N.D. 1 1.17 1.33 117.00 133.00 12.80 HR
Paclobutrazol N.D. 1 1.07 1.28 107.00 128.00 17.87 HR
Parathion-methyl N.D. 1 1.14 1.19 114.00 119.00 4.29
Permethrins N.D. 1 1.06 1.2 106.00 120.00 12.39
Phosmet N.D. 1 1.34 1.49 134.00 149.00 10.60 HR
Piperonyl butoxide N.D. N/A N/A N/A nan nan
Prallethrin N.D. 1 1.26 1.5 126.00 150.00 17.39 HR
Propiconazole N.D. 1 1.15 1.34 115.00 134.00 15.26 HR
Propoxur N.D. 1 1.14 1.89 114.00 189.00 49.50 HRQ
Pyrethrin N.D. 0.58 0.618 0.79 106.55 136.21 24.43 HR
Pyridaben N.D. 1 1.01 1.2 101.00 120.00 17.19
SpinosynA N.D. 0.71 1.07 1.24 150.70 174.65 14.72 HR
SpinosynD N.D. 0.29 0.446 0.554 153.79 191.03 21.60 HR
Spiromesifen N.D. 1 0.861 1.02 86.10 102.00 16.91
Spirotetramat N.D. 1 1.31 1.41 131.00 141.00 7.35 HR
Spiroxamine N.D. 1 1.5 1.81 150.00 181.00 18.73 HR
Tebuconazole N.D. 1 1.11 1.42 111.00 142.00 24.51 HR
Thiacloprid N.D. 1 1.48 1.73 148.00 173.00 15.58 HR
Thiamethoxam N.D. 1 1.59 1.88 159.00 188.00 16.71 HR
Trifloxystrobin N.D. 1 1.21 1.32 121.00 132.00 8.70 HR

N.D. = Not Detected

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 30%

R = indicates compound recovery of matrix spike was outside the methods acceptable limits. (60-120%) Low recovery could indicate there is actually more compound present than detected; while high recoveries should be scrutinized for possible fails as more compound may be detected than is actually residual on the sample.

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
KEB - LM Iron laboratories KEB - LM

Iron Laboratories, LLC is an ISO/IEC 17025:2017 Testing Laboratory laboratory accredited by (PJLA) Perry Johnson Laboratory Accreditation, Certificate No. 77802

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

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