ORELAP     IRON Laboratories     NELAP Accredited Laboratory

ORELAP Cert No. 4092-004
OLCC No. 1002158CD2E

Oregon Compliant Marijuana Potency Analysis by
High Performance Liquid Chromatography
Testing Accreditation #: 4092-004 Test Certificate #: 120531-001
Client Name, Sample Details

45th Parallel Farms #2
Dallas, OR 97338
Sample: Grape City Diesel
License: 100861828BC
Type: Adult Use Flower
Method: FE04U HPLC-UV
Metrc Test Pkg#: 1a40103000023f4000001574
Metrc Source Pkg#: 1a40103000023f4000001519
***Water Activity: 0.566
***Moisture: 13.29%
Test Conditions

Prepsheet ID#: ORP191213a
Scale: XS205-OR1
Temp: 22.3 °C
Baro Pressure: 1003 hPa
Analyst: HRM
Technician: TMR
Sample ID#: 120531

Lot #: Grape City Deisel 10-18-19
Batch #: 120531
Batch Weight (g): 6810
Harvest/Process Date: 10/18/2019
Date Received: 12/13/2019
Test Date: 12/13/2019
Sample #120531
Sample #120531 Sample #120531
Test
Compounds		 THC THCA CBD CBDA CBN CBG CBC THCV* CBDV Total
Cannabinoids*		 Total THC Total CBD Calc Max Total
Cannabinoids*
Amount (%) 0.91 18.92 N/D 0.51 0.82 0.17 0.10 N/D N/D 21.43 17.51 0.45 19.04
Amount (mg/g) 9.13 189.19 N/D 5.09 8.18 1.71 1.02 N/D N/D 214.32 175.05 4.46 190.42
Amount per Serving (mg) N\D N\D N\D N\D N\D N\D N\D N\D N\D 0.00 Serving Size~ (g): 0.00
LOQ (mg/g) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5   %Decarb. THC CBD
±%RPD 8.95 13.22 +/-5% 1.85 11.76 6.30 58.73 +/-5% +/-5% 5 0

LOQ = Limit of Quantitation; %RPD = Relative Percent Deviation; %RSD = Relative Standard Deviation; N/D = Not Detected

*Designates values that are not currently included in the accredited scope of Iron Laboratories.

*** Designates tests that use the method FE-45. FE-45 is performed using AOAC 966.02 and 32.004-32.009. FE-45 has relative expanded (k=2) uncertainties of 1.098% for moisture, 1.754% for water activity for unprocessed plant materials, and 13.102% for water activity for infused products. Vitamin E acetate analysis has a relative expanded (k=2) uncertainty of 18.614%.

Total THC and CBD is the calculated sum of THC or CBD and the amount of THC or CBD derived from THCA or CBDA, respectively. These values are calculated by applying a molar correction factor of 0.877 to the THCA or the CBDA value. Calc Max Total Cannabinoids is the sum of Total THC, Total CBD, CBN, CBG, CBC, THCV, and CBDV.

%Decarb. THC and CBD refer to the percentage of THC or CBD relative to THCA or CBDA, respectively.

SOP FE-01-OR9 was used in accordance with OAR 333-007 for sampling. All marijuana items are sampled and tested in accordance with OAR 333-007-0300 to 333-007-490 and OAR 333-064-0100 to 333-064-0110.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Himashi Mead Iron laboratories Himashi Mead

Iron Labs Oregon complies with 2009 TNI Environmental Laboratory Standards.

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 1 of 4

ORELAP     IRON Laboratories     NELAP Accredited Laboratory

ORELAP Cert No. 4092-004
OLCC No. 1002158CD2E

Oregon Compliant QC Report
Testing Accreditation #: 4092-004 Test Certificate #: 120531-001
Client Name, Sample Details

45th Parallel Farms #2
Dallas, OR 97338
Sample: Grape City Diesel
License: 100861828BC
Type: Adult Use Flower
Method: FE04U HPLC-UV
Metrc Test Pkg#: 1a40103000023f4000001574
Metrc Source Pkg#: 1a40103000023f4000001519
***Water Activity: 0.566
***Moisture: 13.29%
Test Conditions

Prepsheet ID#: ORP191213a
Scale: XS205-OR1
Temp: 22.3 °C
Baro Pressure: 1003 hPa
Analyst: HRM
Technician: TMR
Sample ID#: 120531

Lot #: Grape City Deisel 10-18-19
Batch #: 120531
Batch Weight (g): 6810
Harvest/Process Date: 10/18/2019
Date Received: 12/13/2019
Test Date: 12/13/2019
Sample #120531
Target Compound Name Method Blank (μg/g) LCS Spike (μg/g) LCS Amount (μg/g) Percent Recovery (%) LCS LCS Duplicate Amount (μg/g) Percent Recovery (%) LCSD Relative Percent Difference (%) QC Flag
Cannabidivarin (CBDV) N.D. 1 0 0.00 0 0.00 0
Cannabidiolic Acid (CBDA) N.D. 11.9 10.73 90.17 10.93 91.85 1.85
Cannabigerol (CBG) N.D. 1.77 1.69 95.48 1.8 101.69 6.30
Cannabidiol (CBD) N.D. 1 0 0.00 0 0.00 0
Δ9-Tetrahydrocannabivarin (THCV) N.D. 1 0 0.00 0 0.00 0
Cannabinol (CBN) N.D. 1.44 0.54 37.50 0.48 33.33 11.76
Δ9-Tetrahydrocannabinol (THC) N.D. 30.46 29.88 98.10 32.68 107.29 8.95
Cannabichromene (CBC) N.D. 1.27 0.89 70.08 1.63 128.35 58.73
Tetrahydrocannabinolic acid (THCA) N.D. 158.55 162.78 102.67 142.6 89.94 13.22

N.D. = Not Detected

LR = indicates compound recovery of matrix spike was outside the methods acceptable limits. (70-130%) Low recovery should be scrutinized for possible fail as it could indicate more compound present than is detected.

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 20%

HR = indicates compound recovery of matrix spike was outside the methods acceptable limits. (70-130%) high recoveries should be scrutinized for passing as more compound may be detected than is actually present in the sample.

SOP FE-01-OR9 was used in accordance with OAR 333-007 for sampling. All marijuana items are sampled and tested in accordance with OAR 333-007-0300 to 333-007-490 and OAR 333-064-0100 to 333-064-0110.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Himashi Mead Iron laboratories Himashi Mead

Iron Labs Oregon complies with 2009 TNI Environmental Laboratory Standards.

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 2 of 4

ORELAP     IRON Laboratories     NELAP Accredited Laboratory

ORELAP Cert No. 4092-004
OLCC No. 1002158CD2E

Oregon Compliant Pesticide Analysis by
Mass Spectrometer
Testing Accreditation #: 4092-004 Test Certificate #: 120531-001
Client Name, Sample Details

45th Parallel Farms #2
Dallas, OR 97338
Sample: Grape City Diesel
License: 100861828BC
Type: Adult Use Flower
Method: FE-52 (EN 15662 & AOAC 2007.01)
Metrc Test Pkg#: 1a40103000023f4000001574
Metrc Source Pkg#: 1a40103000023f4000001519
Test Conditions

Prepsheet ID#: ORPS191216a
Scale: XS205-OR1
Temp: 36.7 °C
Baro PE: 1009 hPa
Analyst: HRM
Technician: HRM
Sample ID#: 120531

Lot #: Grape City Deisel 10-18-19
Batch #: 120531
Batch Weight (g): 6810
Harvest/Process Date: 10/18/2019
Date Received: 12/13/2019
Test Date: 12/16/2019
Sample #120531
Compound MRL (µg/g) LOD (µg/g) Status (µg/g)   Compound MRL (µg/g) LOD (µg/g) Status (µg/g)
Aldicarb 0.400 0.124 Pass/<LOD Abamectin**** 0.500 0.124 Pass/<LOD
Acephate 0.400 0.124 Pass/<LOD Acequinocyl 2.000 0.247 Pass/<LOD
Acetamiprid 0.200 0.124 Pass/<LOD Azoxystrobin 0.200 0.124 Pass/<LOD
Bifenazate 0.200 0.124 Pass/<LOD Bifenthrin 0.200 0.124 Pass/<LOD
Boscalid 0.400 0.124 Pass/<LOD Carbaryl 0.200 0.124 Pass/<LOD
Carbofuran 0.200 0.124 Pass/<LOD Chlorantraniliprole 0.200 0.124 Pass/<LOD
Chlorfenapyr 1.000 0.495 Pass/<LOD Chlorpyrifos 0.200 0.124 Pass/<LOD
Clofentezine 0.200 0.124 Pass/<LOD Cyfluthrin** 1.000 0.495 Pass/<LOD
Cypermethrin*** 1.000 0.495 Pass/<LOD Daminozide 1.000 0.124 Pass/<LOD
DDVP (Dichlorvos) 1.000 0.247 Pass/<LOD Diazinon 0.200 0.124 Pass/<LOD
Dimethoate 0.200 0.124 Pass/<LOD Ethoprophos 0.200 0.124 Pass/<LOD
Etofenprox 0.400 0.124 Pass/<LOD Etoxazole 0.200 0.124 Pass/<LOD
Fenoxycarb 0.200 0.124 Pass/<LOD Fenpyroximate 0.400 0.124 Pass/<LOD
Fipronil 0.400 0.124 Pass/<LOD Flonicamid 1.000 0.124 Pass/<LOD
Fludioxonil 0.400 0.124 Pass/<LOD Hexythiazox 1.000 0.124 Pass/<LOD
Imazalil 0.200 0.124 Pass/<LOD Imidacloprid 0.400 0.124 Pass/<LOD
Kresoxim Methyl 0.400 0.124 Pass/<LOD Malathion 0.200 0.124 Pass/<LOD
Metalaxyl 0.200 0.124 Pass/<LOD Methiocarb 0.200 0.124 Pass/<LOD
Methomyl 0.400 0.124 Pass/<LOD Methyl Parathion 0.200 0.124 Pass/<LOD
MGK-264‡ 0.200 0.124 Pass/<LOD Myclobutanil 0.000 0.124 Pass/<LOD
Naled 0.500 0.124 Pass/<LOD Oxamyl 1.000 0.124 Pass/<LOD
Paclobutrazol 0.400 0.124 Pass/<LOD Permethrins† 0.200 0.124 Pass/<LOD
Phosmet 0.200 0.124 Pass/<LOD Piperonyl Butoxide 2.000 0.124 Pass/<LOD
Prallethrin 0.200 0.124 Pass/<LOD Propiconazole 0.400 0.124 Pass/<LOD
Propoxur 0.200 0.124 Pass/<LOD Pyrethrins* 1.000 0.124 Pass/<LOD
Pyridaben 0.200 0.124 Pass/<LOD Spinosad***** 0.200 0.124 Pass/<LOD
Spiromesifen 0.200 0.124 Pass/<LOD Spirotetramat 0.200 0.124 Pass/<LOD
Spiroxamine‡ 0.400 0.124 Pass/<LOD Tebuconazole 0.400 0.124 Pass/<LOD
Thiacloprid 0.200 0.124 Pass/<LOD Thiamethoxam 0.200 0.124 Pass/<LOD
Trifloxystrobin 0.200 0.124 Pass/<LOD

* Pyrethrins are reported as the sum of Jasmolin I, Cinerin I, and Pyrethrin I
** Cyfluthrins are reported as the sum of isomers Cyfluthrin I, II, III, and IV
*** Cypermethrins are reported as the sum of isomers Cypermethrin I, II, III, and IV
**** Abamectin is reported as the sum of Avermectin B1a and Avermectin B1b
***** Spinosad is reported as the sum of Spinosyn A and Spinosyn D
† Permethrin and Prallethrin are reported as the sum of cis and trans isomers
‡ MGK-264 and Spiroximine are reported as the sum of isomers I and II
MRL - Maximum Residue Limit; LOD - Limit of Detection

SOP FE-01-OR9 was used in accordance with OAR 333-007 for sampling. All marijuana items are sampled and tested in accordance with OAR 333-007-0300 to 333-007-490 and OAR 333-064-0100 to 333-064-0110.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Joseph Rutowski Iron laboratories Joseph Rutowski

Iron Labs Oregon complies with 2009 TNI Environmental Laboratory Standards.

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 2 of 4

ORELAP     IRON Laboratories     NELAP Accredited Laboratory

ORELAP Cert No. 4092-004
OLCC No. 1002158CD2E

Oregon Compliant Pesticide QC Report
Testing Accreditation #: 4092-004 Test Certificate #: 120531-001
Client Name, Sample Details

45th Parallel Farms #2
Dallas, OR 97338
Sample: Grape City Diesel
License: 100861828BC
Type: Adult Use Flower
Method: FE-52 (EN 15662 & AOAC 2007.01)
Metrc Test Pkg#: 1a40103000023f4000001574
Metrc Source Pkg#: 1a40103000023f4000001519
Test Conditions

Prepsheet ID#: ORPS191216a
Scale: XS205-OR1
Temp: 36.7 °C
Baro PE: 1009 hPa
Analyst: HRM
Technician: HRM
Sample ID#: 120531

Lot #: Grape City Deisel 10-18-19
Batch #: 120531
Batch Weight (g): 6810
Harvest/Process Date: 10/18/2019
Date Received: 12/13/2019
Test Date: 12/16/2019
Sample #120531
Target Compound Name Method Blank (μg/g) QC Spike (μg/g) Matrix Spike (μg/g) Matrix Spike Duplicate (μg/g) MS recovery% MSD recovery% Relative Percent Difference (%) QC Flag
Acephate N.D. 1 1.12 1.13 112.00 113.00 0.89
Acequinocyl N.D. 1 1.01 0.917 101.00 91.70 9.65
Acetamiprid N.D. 1 1.15 1.18 115.00 118.00 2.58
Aldicarb N.D. 1 1.12 1.15 112.00 115.00 2.64
Avermectin B1a N.D. 0.97 1.21 1.05 124.74 108.25 14.16
Azoxystrobin N.D. 1 1.04 1.08 104.00 108.00 3.77
Bifenazate N.D. 1 0.8 0.814 80.00 81.40 1.73
Bifenthrin N.D. 1 1.17 1.21 117.00 121.00 3.36
Boscalid N.D. 1 0.981 1.03 98.10 103.00 4.87
Carbaryl N.D. 1 1.03 1.04 103.00 104.00 0.97
Carbofuran N.D. 1 1.26 1.24 126.00 124.00 1.60
Chlorantraniliprole N.D. 1 1.14 1.19 114.00 119.00 4.29
Chlorfenapyr N.D. 1 0.715 0.521 71.50 52.10 31.39
Chlorpyriphos N.D. 1 1.03 1.11 103.00 111.00 7.48
Clofentezine N.D. 1 1.01 1.03 101.00 103.00 1.96
Cyfluthrin N.D. 1 1.22 0.872 122.00 87.20 33.27
Cypermethrin N.D. 1 1.33 1.5 133.00 150.00 12.01
Daminoside N.D. 1 0.975 0.795 97.50 79.50 20.34
Diazanon N.D. 1 1.2 1.21 120.00 121.00 0.83
Dichlorvos N.D. 1 1.21 1.24 121.00 124.00 2.45
Dimethoate N.D. 1 1.3 1.3 130.00 130.00 0.00
Ethoprophos N.D. 1 1.09 1.13 109.00 113.00 3.60
Etofenprox N.D. 1 1.17 1.17 117.00 117.00 0.00
Etoxazole N.D. 1 1.14 1.15 114.00 115.00 0.87
Fenoxycarb N.D. 1 1.04 1.08 104.00 108.00 3.77
Fenpyroximate N.D. 1 1.42 1.36 142.00 136.00 4.32
Fipronil N.D. 1 0.891 0.869 89.10 86.90 2.50
Flonicamid N.D. 1 1.26 1.3 126.00 130.00 3.13
Fludioxonil N.D. 1 0.919 0.903 91.90 90.30 1.76
Hexythiazox N.D. 1 0.949 1.04 94.90 104.00 9.15
Imazalil N.D. 1 1.16 1.21 116.00 121.00 4.22
Imidacloprid N.D. 1 1.35 1.38 135.00 138.00 2.20
Kresoxim-methyl N.D. 1 1.02 1.06 102.00 106.00 3.85
Malathion N.D. 1 1.23 1.27 123.00 127.00 3.20
Metalaxyl N.D. 1 1.34 1.47 134.00 147.00 9.25
Methiocarb N.D. 1 1.21 1.22 121.00 122.00 0.82
Methomyl N.D. 1 1.18 1.25 118.00 125.00 5.76
MGK-264 N.D. 1 1.1 1 110.00 100.00 9.52
Myclobutanil N.D. 1 1.18 1.18 118.00 118.00 0.00
Naled (dibrom) N.D. 1 0.63 0.666 63.00 66.60 5.56
Oxamyl N.D. 1 1.46 1.47 146.00 147.00 0.68
Paclobutrazol N.D. 1 1.22 1.29 122.00 129.00 5.58
Parathion-methyl N.D. 1 0.783 0.862 78.30 86.20 9.60
Permethrins N.D. 1 1.25 1.23 125.00 123.00 1.61
Phosmet N.D. 1 1.08 1.11 108.00 111.00 2.74
Piperonyl butoxide N.D. 1 1.12 1.13 112.00 113.00 0.89
Prallethrin N.D. 1 1.17 1.22 117.00 122.00 4.18
Propiconazole N.D. 1 1.07 1.1 107.00 110.00 2.76
Propoxur N.D. 1 1.01 1.02 101.00 102.00 0.99
Pyrethrin N.D. 0.65 0.709 0.706 109.08 108.62 0.42
Pyridaben N.D. 1 1.1 1.05 110.00 105.00 4.65
SpinosynA N.D. 0.84 0.714 0.817 85.00 97.26 13.46
SpinosynD N.D. 0.16 0.175 0.199 109.38 124.38 12.83
Spiromesifen N.D. 1 0.694 0.747 69.40 74.70 7.36
Spirotetramat N.D. 1 0.928 0.985 92.80 98.50 5.96
Spiroxamine N.D. 1 1.24 1.28 124.00 128.00 3.17
Tebuconazole N.D. 1 1.06 1.14 106.00 114.00 7.27
Thiacloprid N.D. 1 1.31 1.33 131.00 133.00 1.52
Thiamethoxam N.D. 1 1.23 1.29 123.00 129.00 4.76
Trifloxystrobin N.D. 1 1.16 1.19 116.00 119.00 2.55

N.D. = Not Detected

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 30%

R = indicates compound recovery of matrix spike was outside the methods acceptable limits. (60-120%) Low recovery could indicate there is actually more compound present than detected; while high recoveries should be scrutinized for possible fails as more compound may be detected than is actually residual on the sample.

SOP FE-01-OR9 was used in accordance with OAR 333-007 for sampling. All marijuana items are sampled and tested in accordance with OAR 333-007-0300 to 333-007-490 and OAR 333-064-0100 to 333-064-0110.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Joseph Rutowski Iron laboratories Joseph Rutowski

Iron Labs Oregon complies with 2009 TNI Environmental Laboratory Standards.

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 3 of 4
IRON Laboratories

Terpene Report by
Mass Spectrometer
Test Certificate #: 120531-001
Client Name, Sample Details

45th Parallel Farms #2
Dallas, OR 97338
Sample: Grape City Diesel
License: 100861828BC
Type: Adult Use Flower
Method: SOP FE-44-OR3
Metrc Test Pkg#: 1a40103000023f4000001574
Metrc Source Pkg#: 1a40103000023f4000001519

Test Conditions

Scale: XS205-OR1
Temp: 21.1 °C
Baro Pressure: 998.9 hPa
Analyst: HRM
Technician: HRM

Sample ID#: 120531

Lot #: Grape City Deisel 10-18-19
Batch #: 120531
Batch Weight (g): 6810
Harvest/Process Date: 10/18/2019
Date Received: 12/13/2019

Sample #120531
Sample #120531
  • α-Pinene (0.05%)
  • β-Ocimene (0.10%)
  • Camphene (0.00%)
  • Eucalyptol (1,8-Cineol) (0.00%)
  • Sabinene (0.00%)
  • γ-Terpinene (0.00%)
  • Myrcene (0.31%)
  • α-Terpinolene (0.03%)
  • β-Pinene (0.08%)
  • Linalool (0.11%)
  • ∆3-Carene (0.00%)
  • Fenchone (0.00%)
  • α-Terpinene (0.00%)
  • endo-Fenchol (0.08%)
  • α-Ocimene (0.00%)
  • Isopulegol (0.00%)
  • Limonene (0.19%)
  • Geraniol (0.00%)
  • p-Cymene (0.00%)
  • β-Caryophyllene (0.36%)
  • α-Humulene (0.18%)
  • Nerolidol 1 (cis) (0.03%)
  • Nerolidol 2 (trans) (0.00%)
  • Guaiol (0.00%)
  • Caryophyllene Oxide (0.03%)
  • α-Bisabolol (0.09%)
  • α-Phellandrene (0.00%)
  • α-Terpineol (0.06%)
  • Valenence (0.00%)

Total: 1.700%

Predominant Terpenes

0.36%   β-Caryophyllene Sweet, woody, spicy, clove 0.31%   Myrcene Peppery, spicy balsam
0.19%   Limonene Citrus, orange, sweet 0.18%   α-Humulene Woody, oceanic-watery, spicy clove
0.11%   Linalool Citrus, floral, sweet, bois de rose, woody, green, blueberry 0.10%   β-Ocimene Citrus, tropical, woody, green

Value in parenthesis indicates percentage of terpene present in the total sample (weight percentage, wt/wt%).
Value in doughnut slice indicates individual terpene abundance with respect to the total terpenes detected.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Joseph Rutowski Iron laboratories Joseph Rutowski

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 4 of 4