IRON Laboratories

Pesticide Analysis by
Mass Spectrometer
Test Certificate #: 117052-001
Client Name, Sample Details

Eric Tomkow
Gaylord, MI 49735
Sample: Green Crack
Type: Flower
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS190528a
Scale: XS205-MI1
Temp: 23.0 °C
Baro PE: 969.2 hPa
Analyst: JRT
Technician: JRT
Sample ID#: 117052

Harvest/Process Date: 05/29/2019
Serving Size (g): 1
Date Received: 05/29/2019
Test Date: 05/28/2019
Valid Through: 05/28/2020
Report Issued: 05/29/2019
Sample #117052
Compound MRL (µg/g) LOD (µg/g) Status (µg/g)   Compound MRL (µg/g) LOD (µg/g) Status (µg/g)
Aldicarb 0.400 0.124 Pass/<LOD Abamectin**** 0.500 0.124 Pass/<LOD
Acephate 0.400 0.124 Pass/<LOD Acequinocyl 2.000 0.248 Pass/<LOD
Acetamiprid 0.200 0.124 Pass/<LOD Azoxystrobin 0.200 0.124 Pass/<LOD
Bifenazate 0.200 0.124 Pass/<LOD Bifenthrin 0.200 0.124 Pass/<LOD
Boscalid 0.400 0.124 Pass/<LOD Carbaryl 0.200 0.124 Pass/<LOD
Carbofuran 0.200 0.124 Pass/<LOD Chlorantraniliprole 0.200 0.124 Pass/<LOD
Chlorfenapyr 1.000 0.496 Pass/<LOD Chlorpyrifos 0.200 0.124 Pass/<LOD
Clofentezine 0.200 0.124 Pass/<LOD Cyfluthrin** 1.000 0.496 Pass/<LOD
Cypermethrin*** 1.000 0.496 Pass/<LOD Daminozide 1.000 0.496 Pass/<LOD
DDVP (Dichlorvos) 1.000 0.248 Pass/<LOD Diazinon 0.200 0.124 Pass/<LOD
Dimethoate 0.200 0.124 Pass/<LOD Ethoprophos 0.200 0.124 Pass/<LOD
Etofenprox 0.400 0.124 Pass/<LOD Etoxazole 0.200 0.124 Pass/<LOD
Fenoxycarb 0.200 0.124 Pass/<LOD Fenpyroximate 0.400 0.124 Pass/<LOD
Fipronil 0.400 0.124 Pass/<LOD Flonicamid 1.000 0.124 Pass/<LOD
Fludioxonil 0.400 0.124 Pass/<LOD Hexythiazox 1.000 0.124 Pass/<LOD
Imazalil 0.200 0.124 Pass/<LOD Imidacloprid 0.400 0.124 Pass/<LOD
Kresoxim Methyl 0.400 0.124 Pass/<LOD Malathion 0.200 0.124 Pass/<LOD
Metalaxyl 0.200 0.124 Pass/<LOD Methiocarb 0.200 0.124 Pass/<LOD
Methomyl 0.400 0.124 Pass/<LOD Methyl Parathion 0.200 0.124 Pass/<LOD
MGK-264‡ 0.200 0.124 Pass/<LOD Myclobutanil 0.200 0.124 Pass/<LOD
Naled 0.500 0.124 Pass/<LOD Oxamyl 1.000 0.124 Pass/<LOD
Paclobutrazol 0.400 0.124 Pass/<LOD Permethrins† 0.200 0.124 Pass/<LOD
Phosmet 0.200 0.124 Pass/<LOD Piperonyl Butoxide 2.000 1.885 Pass/<LOD
Prallethrin 0.200 0.124 Pass/<LOD Propiconazole 0.400 0.124 Pass/<LOD
Propoxur 0.200 0.124 Pass/<LOD Pyrethrins* 1.000 0.124 Pass/<LOD
Pyridaben 0.200 0.124 Pass/<LOD Spinosad***** 0.200 0.124 Pass/<LOD
Spiromesifen 0.200 0.124 Pass/<LOD Spirotetramat 0.200 0.124 Pass/<LOD
Spiroxamine‡ 0.400 0.124 Pass/<LOD Tebuconazole 0.400 0.124 Pass/<LOD
Thiacloprid 0.200 0.124 Pass/<LOD Thiamethoxam 0.200 0.124 Pass/<LOD
Trifloxystrobin 0.200 0.124 Pass/<LOD

* Pyrethrins are reported as the sum of Jasmolin I, Cinerin I, and Pyrethrin I
** Cyfluthrins are reported as the sum of isomers Cyfluthrin I, II, III, and IV
*** Cypermethrins are reported as the sum of isomers Cypermethrin I, II, III, and IV
**** Abamectin is reported as the sum of Avermectin B1a and Avermectin B1b
***** Spinosad is reported as the sum of Spinosyn A and Spinosyn D
† Permethrin and Prallethrin are reported as the sum of cis and trans isomers
‡ MGK-264 and Spiroximine are reported as the sum of isomers I and II
MRL - Maximum Residue Limit; LOD - Limit of Detection

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
MEH QM Iron laboratories MEH QM

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

Page 1 of 3
IRON Laboratories

Pesticide QC Report
Test Certificate #: 117052-001
Client Name, Sample Details

Eric Tomkow
Gaylord, MI 49735
Sample: Green Crack
Type: Flower
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS190528a
Scale: XS205-MI1
Temp: 23.0 °C
Baro PE: 969.2 hPa
Analyst: JRT
Technician: JRT
Sample ID#: 117052

Harvest/Process Date: 05/29/2019
Serving Size (g): 1
Date Received: 05/29/2019
Test Date: 05/28/2019
Valid Through: 05/28/2020
Report Issued: 05/29/2019
Sample #117052
Target Compound Name Method Blank (μg/g) QC Spike (μg/g) Matrix Spike (μg/g) Matrix Spike Duplicate (μg/g) MS recovery% MSD recovery% Relative Percent Difference (%) QC Flag
Acephate N.D. 1 1 1.07 100.00 107.00 6.76
Acequinocyl N.D. 1 0.848 0.852 84.80 85.20 0.47
Acetamiprid N.D. 1 0.994 1.06 99.40 106.00 6.43
Aldicarb N.D. 1 0.976 1.01 97.60 101.00 3.42
Avermectin B1a N.D. 0.97 0.931 0.944 95.98 97.32 1.39
Azoxystrobin N.D. 1 0.87 0.946 87.00 94.60 8.37
Bifenazate N.D. 1 0.641 0.663 64.10 66.30 3.37 LR
Bifenthrin N.D. 1 1.11 1.07 111.00 107.00 3.67
Boscalid N.D. 1 1.02 1.01 102.00 101.00 0.99
Carbaryl N.D. 1 0.957 0.967 95.70 96.70 1.04
Carbofuran N.D. 1 1.02 1.04 102.00 104.00 1.94
Chlorantraniliprole N.D. 1 1.03 1.02 103.00 102.00 0.98
Chlorfenapyr N.D. 1 0.95 1.01 95.00 101.00 6.12
Chlorpyriphos N.D. 1 1.03 1.09 103.00 109.00 5.66
Clofentezine N.D. 1 0.963 1.06 96.30 106.00 9.59
Cyfluthrin N.D. 1 1.04 1.09 104.00 109.00 4.69
Cypermethrin N.D. 1 1.09 1 109.00 100.00 8.61
Daminoside N.D. 1 0.654 0.663 65.40 66.30 1.37 LR
Diazanon N.D. 1 0.979 1.03 97.90 103.00 5.08
Dichlorvos N.D. 1 1 1.03 100.00 103.00 2.96
Dimethoate N.D. 1 1.02 1.05 102.00 105.00 2.90
Ethoprophos N.D. 1 0.941 0.993 94.10 99.30 5.38
Etofenprox N.D. 1 0.962 1.08 96.20 108.00 11.56
Etoxazole N.D. 1 1.1 1.16 110.00 116.00 5.31
Fenoxycarb N.D. 1 0.899 0.962 89.90 96.20 6.77
Fenpyroximate N.D. 1 1.05 1.09 105.00 109.00 3.74
Fipronil N.D. 1 0.997 1.02 99.70 102.00 2.28
Flonicamid N.D. 1 1.03 1.03 103.00 103.00 0.00
Fludioxonil N.D. 1 1.11 1.15 111.00 115.00 3.54
Hexythiazox N.D. 1 0.704 0.734 70.40 73.40 4.17
Imazalil N.D. 1 1.02 1.03 102.00 103.00 0.98
Imidacloprid N.D. 1 1.06 1.09 106.00 109.00 2.79
Kresoxim-methyl N.D. 1 0.996 1.02 99.60 102.00 2.38
Malathion N.D. 1 0.776 0.883 77.60 88.30 12.90
Metalaxyl N.D. 1 0.976 1.03 97.60 103.00 5.38
Methiocarb N.D. 1 0.966 1 96.60 100.00 3.46
Methomyl N.D. 1 0.957 1.05 95.70 105.00 9.27
MGK-264 N.D. 1 1.06 1.09 106.00 109.00 2.79
Myclobutanil N.D. 1 1.08 1.12 108.00 112.00 3.64
Naled (dibrom) N.D. 1 0.562 0.636 56.20 63.60 12.35 LR
Oxamyl N.D. 1 1.03 1.08 103.00 108.00 4.74
Paclobutrazol N.D. 1 0.942 1.02 94.20 102.00 7.95
Parathion-methyl N.D. 1 0.877 0.887 87.70 88.70 1.13
Permethrins N.D. 1 0.722 0.783 72.20 78.30 8.11
Phosmet N.D. 1 0.922 0.987 92.20 98.70 6.81
Piperonyl butoxide N.D. 1 1.07 1.15 107.00 115.00 7.21
Prallethrin N.D. 1 0.908 0.943 90.80 94.30 3.78
Propiconazole N.D. 1 0.911 0.958 91.10 95.80 5.03
Propoxur N.D. 1 0.978 1.07 97.80 107.00 8.98
Pyrethrin N.D. 0.65 0.51 0.543 78.46 83.54 6.27
Pyridaben N.D. 1 0.971 1.07 97.10 107.00 9.70
SpinosynA N.D. 0.84 0.62 0.669 73.81 79.64 7.60
SpinosynD N.D. 0.16 0.127 0.143 79.38 89.38 11.85
Spiromesifen N.D. 1 0.291 0.327 29.10 32.70 11.65 LR
Spirotetramat N.D. 1 0.834 0.918 83.40 91.80 9.59
Spiroxamine N.D. 1 1.18 1.22 118.00 122.00 3.33
Tebuconazole N.D. 1 0.971 0.988 97.10 98.80 1.74
Thiacloprid N.D. 1 1.01 1.12 101.00 112.00 10.33
Thiamethoxam N.D. 1 0.91 1 91.00 100.00 9.42
Trifloxystrobin N.D. 1 0.935 1 93.50 100.00 6.72

N.D. = Not Detected

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 30%

R = indicates compound recovery of matrix spike was outside the methods acceptable limits. (60-120%) Low recovery could indicate there is actually more compound present than detected; while high recoveries should be scrutinized for possible fails as more compound may be detected than is actually residual on the sample.

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
MEH QM Iron laboratories MEH QM

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

Page 2 of 3
IRON Laboratories

Heavy Metals Analysis
Test Certificate #: 117052-001
Client Name, Sample Details

Eric Tomkow
Gaylord, MI 49735
Sample: Green Crack
Type: Flower
Method: FE60 ICPMS-MI
Test Conditions

Analyst: JER
Technician: TAC
Sample ID#: 117052

Harvest/Process Date: 05/29/2019
Serving Size (g): 1
Date Received: 05/29/2019
Report Issued: 06/03/2019
Sample #117052
Test Compound MRL (PPM) LOD (PPM) Status (PPM)
Arsenic 0.2 0.05 Pass/<LOD
Copper Not Tested
Cadmium 0.2 0.05 Pass/<LOD
Chromium 0.6 0.063 Pass/<LOD
Lead 0.5 0.05 Pass/<LOD
Mercury 0.1 0.05 Pass/<LOD
Nickel Not Tested

MRL - Maximum Residue Limit; LOD - Limit of Detection

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
MEH QM Iron laboratories MEH QM

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

Page 3 of 3