IRON Laboratories

Pesticide Analysis by
Mass Spectrometer
Test Certificate #: 116856-001
Client Name, Sample Details

Ananda
Cynthiana, KY 41031
Sample: Gaia 5.8%
Type: Concentrate
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS190510a
Scale: XS205-MI2
Temp: 22.8 °C
Baro PE: 981.3 hPa
Analyst: JRT
Technician: JRT
Sample ID#: 116856

Harvest/Process Date: 05/08/2019
Test Date: 05/10/2019
Valid Through: 05/09/2020
Report Issued: 05/14/2019
Sample #116856
Compound MRL (µg/g) LOD (µg/g) Status (µg/g)   Compound MRL (µg/g) LOD (µg/g) Status (µg/g)
Aldicarb 0.400 0.126 Pass/<LOD Abamectin**** 0.500 0.126 Pass/<LOD
Acephate 0.400 0.126 Pass/<LOD Acequinocyl 2.000 0.252 Pass/<LOD
Acetamiprid 0.200 0.126 Pass/<LOD Azoxystrobin 0.200 0.126 Pass/<LOD
Bifenazate 0.200 0.126 Pass/<LOD Bifenthrin 0.200 0.126 Pass/<LOD
Boscalid 0.400 0.126 Pass/<LOD Carbaryl 0.200 0.126 Pass/<LOD
Carbofuran 0.200 0.126 Pass/<LOD Chlorantraniliprole 0.200 0.126 Pass/<LOD
Chlorfenapyr 1.000 0.505 Pass/<LOD Chlorpyrifos 0.200 0.126 Pass/<LOD
Clofentezine 0.200 0.126 Pass/<LOD Cyfluthrin** 1.000 0.505 Pass/<LOD
Cypermethrin*** 1.000 0.505 Pass/<LOD Daminozide 1.000 0.505 Pass/<LOD
DDVP (Dichlorvos) 1.000 0.252 Pass/<LOD Diazinon 0.200 0.126 Pass/<LOD
Dimethoate 0.200 0.126 Pass/<LOD Ethoprophos 0.200 0.126 Pass/<LOD
Etofenprox 0.400 0.126 Pass/<LOD Etoxazole 0.200 0.126 Pass/<LOD
Fenoxycarb 0.200 0.126 Pass/<LOD Fenpyroximate 0.400 0.126 Pass/<LOD
Fipronil 0.400 0.126 Pass/<LOD Flonicamid 1.000 0.126 Pass/<LOD
Fludioxonil 0.400 0.126 Pass/<LOD Hexythiazox 1.000 0.126 Pass/<LOD
Imazalil 0.200 0.126 Pass/<LOD Imidacloprid 0.400 0.126 Pass/<LOD
Kresoxim Methyl 0.400 0.126 Pass/<LOD Malathion 0.200 0.126 Pass/<LOD
Metalaxyl 0.200 0.126 Pass/<LOD Methiocarb 0.200 0.126 Pass/<LOD
Methomyl 0.400 0.126 Pass/<LOD Methyl Parathion 0.200 0.126 Pass/<LOD
MGK-264‡ 0.200 0.126 Pass/<LOD Myclobutanil 0.200 0.126 Pass/<LOD
Naled 0.500 0.126 Pass/<LOD Oxamyl 1.000 0.126 Pass/<LOD
Paclobutrazol 0.400 0.126 Pass/<LOD Permethrins† 0.200 0.126 Pass/<LOD
Phosmet 0.200 0.126 Pass/<LOD Piperonyl Butoxide 2.000 1.918 Pass/<LOD
Prallethrin 0.200 0.126 Pass/<LOD Propiconazole 0.400 0.126 Pass/<LOD
Propoxur 0.200 0.126 Pass/<LOD Pyrethrins* 1.000 0.126 Pass/<LOD
Pyridaben 0.200 0.126 Pass/<LOD Spinosad***** 0.200 0.126 Pass/<LOD
Spiromesifen 0.200 0.126 Pass/<LOD Spirotetramat 0.200 0.126 Pass/<LOD
Spiroxamine‡ 0.400 0.126 Pass/<LOD Tebuconazole 0.400 0.126 Pass/<LOD
Thiacloprid 0.200 0.126 Pass/<LOD Thiamethoxam 0.200 0.126 Pass/<LOD
Trifloxystrobin 0.200 0.126 Pass/<LOD

* Pyrethrins are reported as the sum of Jasmolin I, Cinerin I, and Pyrethrin I
** Cyfluthrins are reported as the sum of isomers Cyfluthrin I, II, III, and IV
*** Cypermethrins are reported as the sum of isomers Cypermethrin I, II, III, and IV
**** Abamectin is reported as the sum of Avermectin B1a and Avermectin B1b
***** Spinosad is reported as the sum of Spinosyn A and Spinosyn D
† Permethrin and Prallethrin are reported as the sum of cis and trans isomers
‡ MGK-264 and Spiroximine are reported as the sum of isomers I and II
MRL - Maximum Residue Limit; LOD - Limit of Detection

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
MEH QM Iron laboratories MEH QM

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

Page 1 of 2
IRON Laboratories

Pesticide QC Report
Test Certificate #: 116856-001
Client Name, Sample Details

Ananda
Cynthiana, KY 41031
Sample: Gaia 5.8%
Type: Concentrate
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: MIPS190510a
Scale: XS205-MI2
Temp: 22.8 °C
Baro PE: 981.3 hPa
Analyst: JRT
Technician: JRT
Sample ID#: 116856

Harvest/Process Date: 05/08/2019
Test Date: 05/10/2019
Valid Through: 05/09/2020
Report Issued: 05/14/2019
Sample #116856
Target Compound Name Method Blank (μg/g) QC Spike (μg/g) Matrix Spike (μg/g) Matrix Spike Duplicate (μg/g) MS recovery% MSD recovery% Relative Percent Difference (%) QC Flag
Acephate N.D. 1 1.18 1.18 118.00 118.00 0.00
Acequinocyl N.D. 1 0.388 0.443 38.80 44.30 13.24 LR
Acetamiprid N.D. 1 1.05 1.21 105.00 121.00 14.16
Aldicarb N.D. 1 1.2 1.28 120.00 128.00 6.45
Avermectin B1a N.D. 0.97 1.2 0.991 123.71 102.16 19.08
Azoxystrobin N.D. 1 1.3 1.21 130.00 121.00 7.17
Bifenazate N.D. 1 0.392 0.347 39.20 34.70 12.18 LR
Bifenthrin N.D. 1 0.961 0.937 96.10 93.70 2.53
Boscalid N.D. 1 1.05 1.23 105.00 123.00 15.79
Carbaryl N.D. 1 1.2 1.1 120.00 110.00 8.70
Carbofuran N.D. 1 1.24 1.26 124.00 126.00 1.60
Chlorantraniliprole N.D. 1 1 1.25 100.00 125.00 22.22 Q
Chlorfenapyr N.D. 1 1.11 0.763 111.00 76.30 37.05 Q
Chlorpyriphos N.D. 1 0.876 1.01 87.60 101.00 14.21
Clofentezine N.D. 1 0.779 0.914 77.90 91.40 15.95
Cyfluthrin N.D. 1 1.08 0.921 108.00 92.10 15.89
Cypermethrin N.D. 1 0.746 0.913 74.60 91.30 20.13 Q
Daminoside N.D. 1 0.464 0.347 46.40 34.70 28.85 LRQ
Diazanon N.D. 1 1.16 1.22 116.00 122.00 5.04
Dichlorvos N.D. 1 0.994 1.26 99.40 126.00 23.60 Q
Dimethoate N.D. 1 1.18 1.23 118.00 123.00 4.15
Ethoprophos N.D. 1 1.11 1.18 111.00 118.00 6.11
Etofenprox N.D. 1 0.862 0.901 86.20 90.10 4.42
Etoxazole N.D. 1 1.16 1.23 116.00 123.00 5.86
Fenoxycarb N.D. 1 1.12 1.03 112.00 103.00 8.37
Fenpyroximate N.D. 1 0.952 1 95.20 100.00 4.92
Fipronil N.D. 1 1.2 1.2 120.00 120.00 0.00
Flonicamid N.D. 1 0.96 0.994 96.00 99.40 3.48
Fludioxonil N.D. 1 1.13 1.11 113.00 111.00 1.79
Hexythiazox N.D. 1 0.774 0.784 77.40 78.40 1.28
Imazalil N.D. 1 1.25 1.29 125.00 129.00 3.15
Imidacloprid N.D. 1 0.976 1.06 97.60 106.00 8.25
Kresoxim-methyl N.D. 1 0.92 1.25 92.00 125.00 30.41 Q
Malathion N.D. 1 1.23 1.12 123.00 112.00 9.36
Metalaxyl N.D. 1 1.26 1.16 126.00 116.00 8.26
Methiocarb N.D. 1 1.03 1.12 103.00 112.00 8.37
Methomyl N.D. 1 0.946 0.941 94.60 94.10 0.53
MGK-264 N.D. 1 0.927 1.04 92.70 104.00 11.49
Myclobutanil N.D. 1 1.19 1.3 119.00 130.00 8.84
Naled (dibrom) N.D. 1 0.571 0.672 57.10 67.20 16.25 LR
Oxamyl N.D. 1 0.966 0.931 96.60 93.10 3.69
Paclobutrazol N.D. 1 1.18 1.18 118.00 118.00 0.00
Parathion-methyl N.D. 1 1.13 1.03 113.00 103.00 9.26
Permethrins N.D. 1 0.804 0.682 80.40 68.20 16.42 LR
Phosmet N.D. 1 1.09 1.08 109.00 108.00 0.92
Piperonyl butoxide N.D. 1 1.2 1.2 120.00 120.00 0.00
Prallethrin N.D. 1 1.06 1.07 106.00 107.00 0.94
Propiconazole N.D. 1 1.12 1.16 112.00 116.00 3.51
Propoxur N.D. 1 1.23 1.24 123.00 124.00 0.81
Pyrethrin N.D. 0.65 0.67 0.688 103.08 105.85 2.65
Pyridaben N.D. 1 0.995 0.965 99.50 96.50 3.06
SpinosynA N.D. 0.84 0.909 0.986 108.21 117.38 8.13
SpinosynD N.D. 0.16 0.188 0.188 117.50 117.50 0.00
Spiromesifen N.D. 1 0.425 0.453 42.50 45.30 6.38 LR
Spirotetramat N.D. 1 1.08 1.18 108.00 118.00 8.85
Spiroxamine N.D. 1 0.974 0.99 97.40 99.00 1.63
Tebuconazole N.D. 1 1.13 1.19 113.00 119.00 5.17
Thiacloprid N.D. 1 1.08 1.16 108.00 116.00 7.14
Thiamethoxam N.D. 1 0.943 1.07 94.30 107.00 12.62
Trifloxystrobin N.D. 1 1.23 1.3 123.00 130.00 5.53

N.D. = Not Detected

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 30%

R = indicates compound recovery of matrix spike was outside the methods acceptable limits. (60-120%) Low recovery could indicate there is actually more compound present than detected; while high recoveries should be scrutinized for possible fails as more compound may be detected than is actually residual on the sample.

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
MEH QM Iron laboratories MEH QM

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

Page 2 of 2