ORELAPIRON LaboratoriesNELAP Accredited Laboratory

ORELAP Cert No. 4092-002
OLCC No. 1002158CD2E

Hemp Potency Analysis by
High Performance Liquid Chromatography
Testing Accreditation #: 4092-002 Test Certificate #: 114513-001
Client Name, Sample Details

Black Tie CBD
Myrtle Creek, OR 97457
Sample: The Jack Indoor (1)
License: AG-R1045922IHH
Type: Industrial Hemp
Method: FE58RD HPLC1100-OR1
***Moisture: 9.88%
Test Conditions

Scale: XS205-OR1
Temp: 21.7 °C
Baro Pressure: 1015 hPa
Analyst: HRM
Technician: EDT
Sample ID#: 114513

Lot #: R&D
Batch #: 114513
Harvest/Process Date: 01/16/2019
Date Received: 01/17/2019
Test Date: 01/21/2019
Sample #114513
Sample #114513 Sample #114513
Test
Compounds		 CBDV CBDA CBD CBC CBG CBN THCA THCV ∆9-THC Total Cannabinoids
Amount N/D 18.57% 0.80% 0.07% 0.06% N/D 0.68% N/D N/D 20.18%
LOQ 0.05% 0.05% 0.05% 0.05% 0.05% 0.05% 0.05% 0.05% 0.05% Total CBD
Uncertainty ±5% RPD ±5% RPD ±5% RPD ±5% RPD ±5% RPD ±5% RPD ±5% RPD ±5% RPD ±5% RPD 17.09%

THC = Delta-9-THC

LOQ = Limit of Quantitation

RPD is relative percent difference between the LCS and LCS duplicate.

%RPD = Relative Percent Difference; Min. Value = Minimum Detectable Amount, CFU = Colony Forming Units, N/D = Not Detected

*** Designated tests that use the method FE-45.

This sample has not been tested according to OAR 333-007. These results should therefore be used for research and development or quality control purposes only.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Joseph Rutowski Iron laboratories Joseph Rutowski

Iron Labs Oregon complies with 2009 TNI Environmental Laboratory Standards.

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 1 of 5

ORELAPIRON LaboratoriesNELAP Accredited Laboratory

ORELAP Cert No. 4092-002
OLCC No. 1002158CD2E

Pesticide Analysis by
Mass Spectrometer
Testing Accreditation #: 4092-002 Test Certificate #: 114513-001
Client Name, Sample Details

Black Tie CBD
Myrtle Creek, OR 97457
Sample: The Jack Indoor (1)
License: AG-R1045922IHH
Type: Industrial Hemp
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: ORPS190123a
Scale: Veritas-OR1
Temp: 21.4 °C
Baro PE: 1014 hPa
Analyst: JDM
Technician: JDM
Sample ID#: 114513

Lot #: R&D
Batch #: 114513
Harvest/Process Date: 01/16/2019
Date Received: 01/17/2019
Test Date: 01/24/2019
Sample #114513
Compound MRL (µg/g) LOD (µg/g) Status (µg/g)   Compound MRL (µg/g) LOD (µg/g) Status (µg/g)
Aldicarb 0.400 0.121 Pass/<LOD Abamectin**** 0.500 0.121 Pass/<LOD
Acephate 0.400 0.121 Pass/<LOD Acequinocyl 2.000 0.242 Pass/<LOD
Acetamiprid 0.200 0.121 Pass/<LOD Azoxystrobin 0.200 0.121 Pass/<LOD
Bifenazate 0.200 0.121 Pass/<LOD Bifenthrin 0.200 0.121 Pass/<LOD
Boscalid 0.400 0.121 Pass/<LOD Carbaryl 0.200 0.121 Pass/<LOD
Carbofuran 0.200 0.121 Pass/<LOD Chlorantraniliprole 0.200 0.121 Pass/<LOD
Chlorfenapyr 1.000 0.484 Pass/<LOD Chlorpyrifos 0.200 0.121 Pass/<LOD
Clofentezine 0.200 0.121 Pass/<LOD Cyfluthrin** 1.000 0.484 Pass/<LOD
Cypermethrin*** 1.000 0.484 Pass/<LOD Daminozide 1.000 0.121 Pass/<LOD
DDVP (Dichlorvos) 1.000 0.242 Pass/<LOD Diazinon 0.200 0.121 Pass/<LOD
Dimethoate 0.200 0.121 Pass/<LOD Ethoprophos 0.200 0.121 Pass/<LOD
Etofenprox 0.400 0.121 Pass/<LOD Etoxazole 0.200 0.121 Pass/<LOD
Fenoxycarb 0.200 0.121 Pass/<LOD Fenpyroximate 0.400 0.121 Pass/<LOD
Fipronil 0.400 0.121 Pass/<LOD Flonicamid 1.000 0.121 Pass/<LOD
Fludioxonil 0.400 0.121 Pass/<LOD Hexythiazox 1.000 0.121 Pass/<LOD
Imazalil 0.200 0.121 Pass/<LOD Imidacloprid 0.400 0.121 Pass/<LOD
Kresoxim Methyl 0.400 0.121 Pass/<LOD Malathion 0.200 0.121 Pass/<LOD
Metalaxyl 0.200 0.121 Pass/<LOD Methiocarb 0.200 0.121 Pass/<LOD
Methomyl 0.400 0.121 Pass/<LOD Methyl Parathion 0.200 0.121 Pass/<LOD
MGK-264‡ 0.200 0.121 Pass/<LOD Myclobutanil 0.000 0.121 Pass/<LOD
Naled 0.500 0.121 Pass/<LOD Oxamyl 1.000 0.121 Pass/<LOD
Paclobutrazol 0.400 0.121 Pass/<LOD Permethrins† 0.200 0.121 Pass/<LOD
Phosmet 0.200 0.121 Pass/<LOD Piperonyl Butoxide 2.000 0.121 Pass/<LOD
Prallethrin 0.200 0.121 Pass/<LOD Propiconazole 0.400 0.121 Pass/<LOD
Propoxur 0.200 0.121 Pass/<LOD Pyrethrins* 1.000 0.121 Pass/<LOD
Pyridaben 0.200 0.121 Pass/<LOD Spinosad***** 0.200 0.121 Pass/<LOD
Spiromesifen 0.200 0.121 Pass/<LOD Spirotetramat 0.200 0.121 Pass/<LOD
Spiroxamine‡ 0.400 0.121 Pass/<LOD Tebuconazole 0.400 0.121 Pass/<LOD
Thiacloprid 0.200 0.121 Pass/<LOD Thiamethoxam 0.200 0.121 Pass/<LOD
Trifloxystrobin 0.200 0.121 Pass/<LOD

* Pyrethrins are reported as the sum of Jasmolin I, Cinerin I, and Pyrethrin I
** Cyfluthrins are reported as the sum of isomers Cyfluthrin I, II, III, and IV
*** Cypermethrins are reported as the sum of isomers Cypermethrin I, II, III, and IV
**** Abamectin is reported as the sum of Avermectin B1a and Avermectin B1b
***** Spinosad is reported as the sum of Spinosyn A and Spinosyn D
† Permethrin and Prallethrin are reported as the sum of cis and trans isomers
‡ MGK-264 and Spiroximine are reported as the sum of isomers I and II
MRL - Maximum Residue Limit; LOD - Limit of Detection

This sample has not been tested according to OAR 333-007. These results should therefore be used for research and development or quality control purposes only.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Joseph Rutowski Iron laboratories Joseph Rutowski

Iron Labs Oregon complies with 2009 TNI Environmental Laboratory Standards.

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 2 of 5

ORELAPIRON LaboratoriesNELAP Accredited Laboratory

ORELAP Cert No. 4092-002
OLCC No. 1002158CD2E

Pesticide QC Report
Testing Accreditation #: 4092-002 Test Certificate #: 114513-001
Client Name, Sample Details

Black Tie CBD
Myrtle Creek, OR 97457
Sample: The Jack Indoor (1)
License: AG-R1045922IHH
Type: Industrial Hemp
Method: FE-52 (EN 15662 & AOAC 2007.01)
Test Conditions

Prepsheet ID#: ORPS190123a
Scale: Veritas-OR1
Temp: 21.4 °C
Baro PE: 1014 hPa
Analyst: JDM
Technician: JDM
Sample ID#: 114513

Lot #: R&D
Batch #: 114513
Harvest/Process Date: 01/16/2019
Date Received: 01/17/2019
Test Date: 01/24/2019
Sample #114513
Target Compound Name Method Blank (μg/g) QC Spike (μg/g) Matrix Spike (μg/g) Matrix Spike Duplicate (μg/g) MS recovery% MSD recovery% Relative Percent Difference (%) QC Flag
Acephate N.D. 1 0.911 0.968 91.10 96.80 6.07
Acequinocyl N.D. 1 0.765 0.705 76.50 70.50 8.16
Acetamiprid N.D. 1 0.91 0.88 91.00 88.00 3.35
Aldicarb N.D. 1 0.979 0.937 97.90 93.70 4.38
Avermectin B1a N.D. 0.97 0.851 0.939 87.73 96.80 9.83
Azoxystrobin N.D. 1 0.714 0.71 71.40 71.00 0.56
Bifenazate N.D. 1 0.605 0.719 60.50 71.90 17.22 LR
Bifenthrin N.D. 1 0.738 0.81 73.80 81.00 9.30
Boscalid N.D. 1 0.668 0.77 66.80 77.00 14.19 LR
Carbaryl N.D. 1 0.926 0.913 92.60 91.30 1.41
Carbofuran N.D. 1 0.9 0.867 90.00 86.70 3.74
Chlorantraniliprole N.D. 1 0.6 0.702 60.00 70.20 15.67 LR
Chlorfenapyr N.D. 1 0.854 0.802 85.40 80.20 6.28
Chlorpyriphos N.D. 1 0.86 0.939 86.00 93.90 8.78
Clofentezine N.D. 1 0.565 0.684 56.50 68.40 19.06 LR
Cyfluthrin N.D. 1 0.694 0.788 69.40 78.80 12.69 LR
Cypermethrin N.D. 1 0.746 0.857 74.60 85.70 13.85
Daminoside N.D. 1 0.426 0.468 42.60 46.80 9.40 LR
Diazanon N.D. 1 0.562 0.668 56.20 66.80 17.24 LR
Dichlorvos N.D. 1 0.843 0.857 84.30 85.70 1.65
Dimethoate N.D. 1 0.909 0.857 90.90 85.70 5.89
Ethoprophos N.D. 1 0.703 0.674 70.30 67.40 4.21 LR
Etofenprox N.D. 1 0.827 0.81 82.70 81.00 2.08
Etoxazole N.D. 1 0.881 0.944 88.10 94.40 6.90
Fenoxycarb N.D. 1 0.624 0.746 62.40 74.60 17.81 LR
Fenpyroximate N.D. 1 0.966 0.959 96.60 95.90 0.73
Fipronil N.D. 1 0.939 0.95 93.90 95.00 1.16
Flonicamid N.D. 1 0.855 0.829 85.50 82.90 3.09
Fludioxonil N.D. 1 1 0.94 100.00 94.00 6.19
Hexythiazox N.D. 1 0.592 0.545 59.20 54.50 8.27 LR
Imazalil N.D. 1 0.633 0.755 63.30 75.50 17.58 LR
Imidacloprid N.D. 1 0.83 0.895 83.00 89.50 7.54
Kresoxim-methyl N.D. 1 0.569 0.674 56.90 67.40 16.89 LR
Malathion N.D. 1 0.653 0.789 65.30 78.90 18.86 LR
Metalaxyl N.D. 1 0.73 0.813 73.00 81.30 10.76
Methiocarb N.D. 1 0.838 0.762 83.80 76.20 9.50
Methomyl N.D. 1 0.713 0.887 71.30 88.70 21.75 Q
MGK-264 N.D. 1 0.573 0.68 57.30 68.00 17.08 LR
Myclobutanil N.D. 1 0.654 0.803 65.40 80.30 20.45 LRQ
Naled (dibrom) N.D. 1 0.692 0.647 69.20 64.70 6.72 LR
Oxamyl N.D. 1 0.839 0.839 83.90 83.90 0.00
Paclobutrazol N.D. 1 0.638 0.764 63.80 76.40 17.97 LR
Parathion-methyl N.D. 1 0.836 0.832 83.60 83.20 0.48
Permethrins N.D. 1 0.865 0.88 86.50 88.00 1.72
Phosmet N.D. 1 0.642 0.768 64.20 76.80 17.87 LR
Piperonyl butoxide N.D. 1 0.925 0.961 92.50 96.10 3.82
Prallethrin N.D. 1 0.543 0.656 54.30 65.60 18.85 LR
Propiconazole N.D. 1 0.653 0.723 65.30 72.30 10.17 LR
Propoxur N.D. 1 0.986 0.954 98.60 95.40 3.30
Pyrethrin N.D. 0.65 0.428 0.476 65.85 73.23 10.62 LR
Pyridaben N.D. 1 0.815 0.863 81.50 86.30 5.72
SpinosynA N.D. 0.84 0.619 0.702 73.69 83.57 12.57
SpinosynD N.D. 0.16 0.135 0.133 84.38 83.13 1.49
Spiromesifen N.D. 1 0.365 0.385 36.50 38.50 5.33 LR
Spirotetramat N.D. 1 0.724 0.742 72.40 74.20 2.46
Spiroxamine N.D. 1 0.704 0.808 70.40 80.80 13.76
Tebuconazole N.D. 1 0.595 0.744 59.50 74.40 22.26 LRQ
Thiacloprid N.D. 1 0.776 0.8 77.60 80.00 3.05
Thiamethoxam N.D. 1 0.647 0.752 64.70 75.20 15.01 LR
Trifloxystrobin N.D. 1 0.84 0.838 84.00 83.80 0.24

N.D. = Not Detected

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 30%

R = indicates compound recovery of matrix spike was outside the methods acceptable limits. (60-120%) Low recovery could indicate there is actually more compound present than detected; while high recoveries should be scrutinized for possible fails as more compound may be detected than is actually residual on the sample.

This sample has not been tested according to OAR 333-007. These results should therefore be used for research and development or quality control purposes only.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Joseph Rutowski Iron laboratories Joseph Rutowski

Iron Labs Oregon complies with 2009 TNI Environmental Laboratory Standards.

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 3 of 5
IRON Laboratories

Terpene Report by
Mass Spectrometer
Test Certificate #: 114513-001
Client Name, Sample Details

Black Tie CBD
Myrtle Creek, OR 97457
Sample: The Jack Indoor (1)
License: AG-R1045922IHH
Type: Industrial Hemp
Method: SOP FE-44-OR3
Test Conditions

Scale: XS205-OR1
Temp: 19.1 °C
Baro Pressure: 1001 hPa
Analyst: HRM
Technician: HRM
Sample ID#: 114513

Lot #: R&D
Batch #: 114513
Harvest/Process Date: 01/16/2019
Date Received: 01/17/2019
Test Date: 01/25/2019
Sample #114513

Mono Terpenes

Weight Percentage Dry Matter (wt/wt%)

α-Pinene:

0.030 %

β-Ocimene:

0.060 %

Camphene:

 N/D

Eucalyptol (1,8-Cineol):

 N/D

Sabinene:

 N/D

γ-Terpinene:

 N/D

Myrcene:

0.170 %

α-Terpinolene:

 N/D

β-Pinene:

0.030 %

Linalool:

0.020 %

∆3-Carene:

 N/D

Fenchone:

 N/D

α-Terpinene:

 N/D

Fenchol:

0.020 %

Ocimene:

 N/D

Isopulegol:

 N/D

Limonene:

0.050 %

Geraniol:

 N/D

4-Cymene:

 N/D

Sequi Terpenes

Weight Percentage Dry Matter (wt/wt%)

β-Caryophyllene:

0.180 %

α-Humulene:

0.100 %

Nerolidol 1:

 N/D

Nerolidol 2:

 N/D

Guaiol:

0.060 %

Caryophyllene Oxide:

0.020 %

α-Bisabolol:

0.080 %

Other Terpenes

Total: 0.820%
a-Phellandrene = 0.00 % a-Terpineol = 0.02 % Valencene = 0.00 %

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
Joseph Rutowski Iron laboratories Joseph Rutowski

Tested by Iron Laboratories Oregon, 71 Centennial Loop Suite D Eugene, OR 97401

Page 4 of 5
IRON Laboratories

Heavy Metals Analysis
Test Certificate #: 114513-001
Client Name, Sample Details

Black Tie CBD
Myrtle Creek, OR 97457
Sample: The Jack Indoor (1)
License: AG-R1045922IHH
Type: Industrial Hemp
Method: FE60 ICPMS-MI
Test Conditions

Analyst: JER
Technician: TAC
Sample ID#: 114513

Lot #: R&D
Batch #: 114513
Harvest/Process Date: 01/16/2019
Date Received: 01/17/2019
Report Issued: 02/12/2019
Sample #114513
Sample #114513 Sample #114513
Test Compound MRL (PPM) LOD (PPM) Status (PPM)
Arsenic 0.2 0.05 Pass/0.000
Copper Not Tested
Cadmium 0.2 0.05 Pass/0.051
Chromium 0.6 0.05 Pass/0.238
Lead 0.5 0.05 Pass/0.127
Mercury 0.1 0.05 Pass/0.000
Nickel Not Tested

MRL - Maximum Residue Limit; LOD - Limit of Detection

This sample has not been tested according to OAR 333-007. These results should therefore be used for research and development or quality control purposes only.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
MEH QM Iron laboratories MEH QM

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

Page 5 of 5