IRON Laboratories     PJLA

ISO/IEC 17025:2017 Accredited

Marihuana Potency Analysis by
High Performance Liquid Chromatography
Testing Accreditation #: 77802 Test Certificate #: 143480-001
Client Name, Sample Details

Pinebrook Warren LLC K-Zoo AU-G-C-000546
Kalamazoo, MI 49004
Sample: Pineapple OG
License: AU-G-C-000546
Type: Adult Use Flower
Method: FE04U12 HPLC-UV
Metrc Test Pkg#: 1A4050300021AB1000032979
Metrc Source Pkg#: 1A4050300021AB1000032935
***Water Activity: 0.46
Test Conditions

Prepsheet ID#: MIP231108c
Scale: XS205-MI2
Temp: 22.5 °C
Baro Pressure: 978.1 hPa
Analyst: ARH
Technician: ARH
Sample ID#: 143480

Harvest/Process Date: 11/07/2023
Serving Size (g): 1
Date Received: 11/07/2023
Test Date: 11/08/2023
Valid Through: 11/08/2024
Report Issued: 11/10/2023
Sample #143480
Sample #143480 Sample #143480
Test
Compounds		 Δ9-THC THCA Δ8-THC CBD CBDA CBG CBGA CBN CBC CBL THCV CBDV Total
Cannabinoids*		 Total THC Total CBD Calc Max Total
Cannabinoids*
Amount (%) 1.0 27.3 N/D N/D N/D N/D 1.0 N/D N/D 0.2 N/D N/D 29.4 24.9 0.0 26.0
Amount (mg/g) 9.9 273.1 N/D N/D N/D N/D 9.54 N/D N/D 1.8 N/D N/D 294.34 249.4 0.0 259.6
Amount per Serving (mg) 9.9 273.1 N/D N/D N/D N/D 9.54 N/D N/D 1.8 N/D N/D 294.3 Serving Size~ (g): 1.0
LOQ (mg/g) 0.76 0.76 0.76 0.76 0.76 0.76 0.76 0.76 0.76 0.76 0.76 0.76   %Decarb. THC CBD
±%RPD 4.14% 0.43% 2.76% 1.03% 0.25% 0.68% 0.64% 3.00% 1.56% 8.03% 0.29% 0.80% 4 N/A

Sample passes for water activity (sample fails if Aw>0.65).

LOQ = Limit of Quantitation; %RPD = Relative Percent Deviation; %RSD = Relative Standard Deviation; N/D = Not Detected

*Designates values that are not currently included in the accredited scope of Iron Laboratories.

*** Designates tests that use the method FE-45. FE-45 is performed using AOAC 966.02 and 32.004-32.009.

FE-45 has relative expanded (k=2) uncertainties of 1.098% for moisture, 1.754% for water activity for unprocessed plant materials, and 13.102% for water activity for infused products.

Vitamin E acetate analysis has a relative expanded (k=2) uncertainty of 18.614%.

Total THC and CBD is the calculated sum of Δ9-THC and Δ8-THC or CBD plus the amount of THC or CBD derived from THCA or CBDA, respectively.

These values are calculated by applying a molar correction factor of 0.877 to the THCA or the CBDA value.

Calc Max Total Cannabinoids is the sum of Total THC, Total CBD, CBN, Total CBG, CBC, THCV, CBDV, and CBL.

Total CBG is calculated as CBG plus CBGA*0.878 (the molar correction factor for CBGA to CBG conversion).

%Decarb. THC and CBD refer to the percentage of Δ9-THC or CBD relative to THCA or CBDA, respectively.

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
ARH - LM Iron laboratories ARH - LM

Iron Laboratories, LLC is an ISO/IEC 17025:2017 Testing Laboratory laboratory accredited by (PJLA) Perry Johnson Laboratory Accreditation, Certificate No. 77802

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

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IRON Laboratories     PJLA

ISO/IEC 17025:2017 Accredited

QC Report
Testing Accreditation #: 77802 Test Certificate #: 143480-001
Client Name, Sample Details

Pinebrook Warren LLC K-Zoo AU-G-C-000546
Kalamazoo, MI 49004
Sample: Pineapple OG
License: AU-G-C-000546
Type: Adult Use Flower
Method: FE04U12 HPLC-UV
Metrc Test Pkg#: 1A4050300021AB1000032979
Metrc Source Pkg#: 1A4050300021AB1000032935
***Water Activity: 0.46
Test Conditions

Prepsheet ID#: MIP231108c
Scale: XS205-MI2
Temp: 22.5 °C
Baro Pressure: 978.1 hPa
Analyst: ARH
Technician: ARH
Sample ID#: 143480

Harvest/Process Date: 11/07/2023
Serving Size (g): 1
Date Received: 11/07/2023
Test Date: 11/08/2023
Valid Through: 11/08/2024
Report Issued: 11/10/2023
Sample #143480
Target Compound Name Method Blank (μg/g) LCS Spike (μg/g) LCS Amount (μg/g) Percent Recovery (%) LCS LCS Duplicate Amount (μg/g) Percent Recovery (%) LCSD Relative Percent Difference (%) QC Flag
Δ9-THC 0 4.9815 5.08313 102.04 5.29808 106.36 4.14%
THCA 0 4.45096 4.45865 100.17 4.47806 100.61 0.43%
Δ8-THC 0 5.10105 4.78251 93.76 4.91658 96.38 2.76%
CBD 0 5.00465 4.91658 98.24 4.86629 97.24 1.03%
CBDA 0 4.5366 4.51211 99.46 4.52352 99.71 0.25%
CBG 0 5.25718 5.21468 99.19 5.25021 99.87 0.68%
CBGA 0 4.65328 4.59641 98.78 4.56715 98.15 0.64%
CBN 0 4.95158 5.03556 101.70 4.88673 98.69 3.00%
CBC 0 4.52264 4.8171 106.51 4.74269 104.87 1.56%
CBCA 0 0 0 0.00 0 0.00 0%
CBL 0 5.35419 4.8417 90.43 4.46778 83.44 8.03% LR
THCV 0 4.90366 4.88438 99.61 4.87011 99.32 0.29%
CBDV 0 5.85825 4.63967 79.20 4.60249 78.56 0.80% LR

N.D. = Not Detected

LR = indicates compound recovery of matrix spike was outside the methods acceptable limits. (70-130%) Low recovery should be scrutinized for possible fail as it could indicate more compound present than is detected.

I = indicates that an amount of an interfering compound greater than the methods limit of detection was detected in the method blank sample. May indicate contamination of analytical system or consumables.

Q = indicates that the relative percent diference of two identicly prepared Matrix Spike samples for a target analyte was greater than 20%

HR = indicates compound recovery of matrix spike was outside the methods acceptable limits. (70-130%) high recoveries should be scrutinized for passing as more compound may be detected than is actually present in the sample.

Sample was sampled and tested in accordance with the Safety Compliance Facility Sampling and Testing Information.

This certificate shall not be reproduced except in full, without written approval of Iron Laboratories, LLC.
ARH - LM Iron laboratories ARH - LM

Iron Laboratories, LLC is an ISO/IEC 17025:2017 Testing Laboratory laboratory accredited by (PJLA) Perry Johnson Laboratory Accreditation, Certificate No. 77802

Tested by Iron Laboratories Michigan, 1825 E. West Maple Walled Lake, MI 48390

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